Matches in SemOpenAlex for { <https://semopenalex.org/work/W2368809887> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2368809887 abstract "High performance liquid chromatography (HPLC) has been widely considered as the most effective way for the separation and preparation of optically pure enantiomers. In the resolution by HPLC, the separation ability of a column strongly depends on the properties of a chiral stationary phase (CSP). Among many CSPs, the immobilized CSPs, which are becoming one of the most important kinds of CSPs, have the advantages of good solvent durability and enormous method flexibility. In this work, a novel optically active acrylamide derivative (S)-APACP was synthesized by two-step reactions, and its chemical structure was characterized by 1H NMR. The polyacrylamide derivatives were immobilized on silica gel by three-step reactions to prepare immobilized CSPs, and the immobilization amount of the polymers was tested by thermogravimetric analysis. The chiral recognition ability of the immobilized CSPs was evaluated by HPLC, and the effects of Lewis acid and mobile phase on the chiral recognition ability were investigated. The results showed that APACP polymer was successfully immobilized on silica gel to prepare immobilized-type CSP with better solvent durability, and the amount of immobilized polymer was 10. 2% to 11. 8%. The immobilized-type CSP showed good chiral recognition ability for several enantiomers." @default.
- W2368809887 created "2016-06-24" @default.
- W2368809887 creator A5011116647 @default.
- W2368809887 creator A5025402999 @default.
- W2368809887 creator A5032914474 @default.
- W2368809887 creator A5043671267 @default.
- W2368809887 creator A5044958541 @default.
- W2368809887 creator A5050020430 @default.
- W2368809887 creator A5052843754 @default.
- W2368809887 creator A5085713706 @default.
- W2368809887 creator A5086699090 @default.
- W2368809887 date "2016-01-01" @default.
- W2368809887 modified "2023-10-18" @default.
- W2368809887 title "Preparation and chiral recognition ability of chiral stationary phase based on immobilized polyacrylamide derivative" @default.
- W2368809887 doi "https://doi.org/10.3724/sp.j.1123.2015.10036" @default.
- W2368809887 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27319168" @default.
- W2368809887 hasPublicationYear "2016" @default.
- W2368809887 type Work @default.
- W2368809887 sameAs 2368809887 @default.
- W2368809887 citedByCount "0" @default.
- W2368809887 crossrefType "journal-article" @default.
- W2368809887 hasAuthorship W2368809887A5011116647 @default.
- W2368809887 hasAuthorship W2368809887A5025402999 @default.
- W2368809887 hasAuthorship W2368809887A5032914474 @default.
- W2368809887 hasAuthorship W2368809887A5043671267 @default.
- W2368809887 hasAuthorship W2368809887A5044958541 @default.
- W2368809887 hasAuthorship W2368809887A5050020430 @default.
- W2368809887 hasAuthorship W2368809887A5052843754 @default.
- W2368809887 hasAuthorship W2368809887A5085713706 @default.
- W2368809887 hasAuthorship W2368809887A5086699090 @default.
- W2368809887 hasConcept C106159729 @default.
- W2368809887 hasConcept C111771559 @default.
- W2368809887 hasConcept C15920480 @default.
- W2368809887 hasConcept C162324750 @default.
- W2368809887 hasConcept C16838498 @default.
- W2368809887 hasConcept C178790620 @default.
- W2368809887 hasConcept C179998833 @default.
- W2368809887 hasConcept C185592680 @default.
- W2368809887 hasConcept C188027245 @default.
- W2368809887 hasConcept C21951064 @default.
- W2368809887 hasConcept C2778862431 @default.
- W2368809887 hasConcept C2779402116 @default.
- W2368809887 hasConcept C2779532046 @default.
- W2368809887 hasConcept C2780471494 @default.
- W2368809887 hasConcept C2993377673 @default.
- W2368809887 hasConcept C43617362 @default.
- W2368809887 hasConcept C44280652 @default.
- W2368809887 hasConcept C486523 @default.
- W2368809887 hasConcept C521977710 @default.
- W2368809887 hasConceptScore W2368809887C106159729 @default.
- W2368809887 hasConceptScore W2368809887C111771559 @default.
- W2368809887 hasConceptScore W2368809887C15920480 @default.
- W2368809887 hasConceptScore W2368809887C162324750 @default.
- W2368809887 hasConceptScore W2368809887C16838498 @default.
- W2368809887 hasConceptScore W2368809887C178790620 @default.
- W2368809887 hasConceptScore W2368809887C179998833 @default.
- W2368809887 hasConceptScore W2368809887C185592680 @default.
- W2368809887 hasConceptScore W2368809887C188027245 @default.
- W2368809887 hasConceptScore W2368809887C21951064 @default.
- W2368809887 hasConceptScore W2368809887C2778862431 @default.
- W2368809887 hasConceptScore W2368809887C2779402116 @default.
- W2368809887 hasConceptScore W2368809887C2779532046 @default.
- W2368809887 hasConceptScore W2368809887C2780471494 @default.
- W2368809887 hasConceptScore W2368809887C2993377673 @default.
- W2368809887 hasConceptScore W2368809887C43617362 @default.
- W2368809887 hasConceptScore W2368809887C44280652 @default.
- W2368809887 hasConceptScore W2368809887C486523 @default.
- W2368809887 hasConceptScore W2368809887C521977710 @default.
- W2368809887 hasLocation W23688098871 @default.
- W2368809887 hasLocation W23688098872 @default.
- W2368809887 hasOpenAccess W2368809887 @default.
- W2368809887 hasPrimaryLocation W23688098871 @default.
- W2368809887 hasRelatedWork W2002360611 @default.
- W2368809887 hasRelatedWork W2018369983 @default.
- W2368809887 hasRelatedWork W2018766752 @default.
- W2368809887 hasRelatedWork W2021792606 @default.
- W2368809887 hasRelatedWork W2033065387 @default.
- W2368809887 hasRelatedWork W2041999332 @default.
- W2368809887 hasRelatedWork W2106932605 @default.
- W2368809887 hasRelatedWork W2372970552 @default.
- W2368809887 hasRelatedWork W2377982157 @default.
- W2368809887 hasRelatedWork W2951679339 @default.
- W2368809887 isParatext "false" @default.
- W2368809887 isRetracted "false" @default.
- W2368809887 magId "2368809887" @default.
- W2368809887 workType "article" @default.