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- W2368812101 abstract "The relationship between molar constant heat capacity and temperature of ethyl nitrite was induced by Joback group contribution method,and the standard molar formation Gibbs free energy of ethyl nitrite and diethyl carbonate was also estimated by this method respectively.Reaction enthalpy change,reaction Gibbs free energy change and equilibrium constant of relevant reactions occurred in the process for CO coupling to diethyl oxalate were calculated and analyzed together with basic chemical thermodynamic data obtained from chemistry and engineer handbooks.The result shows that the lower temperature is advantageous to the formation of diethyl oxalate,and the reaction degree of the main reaction is much higher than that of the side reaction." @default.
- W2368812101 created "2016-06-24" @default.
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- W2368812101 date "2011-01-01" @default.
- W2368812101 modified "2023-09-23" @default.
- W2368812101 title "Thermodynamic analysis of process for CO coupling to diethyl oxalate" @default.
- W2368812101 hasPublicationYear "2011" @default.
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