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- W2369593368 abstract "Activity coefficients at infinite dilution,γ 1,3∞ (where 1 refers to solutes and 3 to solvent),were determined for 27 solutes including alkanes,aromatics,chlorinated methane,alcohols,ketone,ether,ester acetonitrile,triethylamine,carbon disulfide,tetrahydrofuran,morpholine,pyridine and water in the ionic liquid 1-ethyl-3-methylimidazolium dicyanamide ([EMIM] [N(CN)2]). The measurements were carried out respectively at temperatures of 323.15K,333.15K,343.15K and 353.15 K by using inverse gas chromatography with the ionic liquid as stationary phase. The selectivity of [EMIM] [N(CN)2] defined as the ratio of γ 1,3 ∞ to γ 2,3 ∞ was studied to examine the potential use of the above ionic liquid as an extractant or entrainer for the separation of azeotropic systems. The results show that 1-ethyl-3-methylimidazolium dicyanamide is a suitable solvent for the separation of binary aqueous azeotropes and the systems with large asymmetric polarity. In addition,via the relationship between the γ1,3 ∞ values and temperature,the partial excess molar enthalpies at infinite dilution (Hi E,∞) of solutes in the mentioned ionic liquid were estimated." @default.
- W2369593368 created "2016-06-24" @default.
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- W2369593368 date "2008-01-01" @default.
- W2369593368 modified "2023-09-28" @default.
- W2369593368 title "Measurement of Infinite Diluted Activity Coefficient of Solutes in 1-Ethyl-3-methylimidazolium Dicyanamide" @default.
- W2369593368 hasPublicationYear "2008" @default.
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