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- W2369982609 abstract "The adsorption characteristics and mechanism of Pb~(2+) by inactive Phanerochaete chrysosporium mycelial pellets were studied.The results showed that the adsorption of Pb~(2+) by inactive P.chrysosporium belonged to monolayer surface adsorption.The Langmuir model described the biosorption equilibrium of Pb~(2+) on mycelial pellets better than the Freundlich model.The adsorption dynamics suggested that there were two stages in the process of biosorption of Pb~(2+):a faster sorption step followed by slower uptake.The biosorption dynamics of Pb~(2+) by mycelial pellets could be described using pseudo second-order adsorption kinetics,and the intraparticle diffusion was not the rate-controlling step.The biosorption process of Pb~(2+)was exothermic,and the activation energy for the biosorption of Pb~(2+) was-35.78(kJmol.) The enthalpy change of the biosorption of Pb~(2+) was near to that of the chemical reaction,which was-44.45(kJmol.) The complex reaction between oxygenous functional groups on the cell wall and Pb~(2+) adsorbed on the surface of cells,and the exchange between Pb~(2+) and H~+ on the cell wall,were proved to exist in the process of biosorption of Pb~(2+)." @default.
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- W2369982609 date "2010-01-01" @default.
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- W2369982609 title "Biosorption Characteristics and Mechanism of Pb~(2+) by Phanerochaete chrysosporium" @default.
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