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- W2370105417 abstract "MCM-56 zeolite was prepared by hydrothermally dynamic method. The as-made MCM-56 was detemplated by treating with a 30%H2O2 solution to obtain MCM-56(H2O2) zeolite instead of being treated with high-temperature calcination. The structure and acid properties of samples were studied by means of XRD, N2 adsorption-desorption, NH3-TPD and FTIR. The BET surface area of MCM-56(H2O2) can be improved significantly by hydrogen peroxide detemplation. A higher external surface area of 301 cm2/g was obtained for HMCM-56(H2O2) compared with 134 cm2/g for HMCM-56(C). The amount of acid sites has been increased by hydrogen peroxide treatment, while the acid strength has not been modified. Both the HMCM-56 zeolite detemplated by H2O2 and by calcination were used in benzene alkylation with propylene in liquid phase. Under our operation condition, HMCM-56(H2O2) shows a relative high activity and selectivity to cumene than HMCM-56(C), especially under a relative low reaction temperature and benzene-to-propylene molar ratio." @default.
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- W2370105417 date "2009-07-10" @default.
- W2370105417 modified "2023-09-25" @default.
- W2370105417 title "Catalytic Performance of MCM-56 Molecular Sieve for Benzene Alkylation with Propylene" @default.
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