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- W2370292770 abstract "A new synthetic method featuring using 5 - sulfosalicylic acid as catalyst to prepare nine titanocene derivatives is reported. The title complexes were characterized by elemental analysis, UV - vis, IR and 1H NMR spectroscopy. Based on the UV - vis spectrum, the mechanism of synthetic complexes is proposed as follows: first, Cp2TiCl2 in the organic phase reacts interfacially with 5 - sulfosalicylic acid in the aqueons phase to form an intermediate. The resulting species undergoes an interfacial interaction with substituted salicylic acid to form the final complexes, which stay in the organic phase. Then the 'Cp2Ti' species return to the organic phase while 5 - sulfosalicylic acid remains in the water phase." @default.
- W2370292770 created "2016-06-24" @default.
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- W2370292770 date "2000-01-01" @default.
- W2370292770 modified "2023-09-23" @default.
- W2370292770 title "Synthesis of Titanocene Derivatives Catalyzed by 5 - Sulfosalicylic Acid in a Two - Phase System" @default.
- W2370292770 hasPublicationYear "2000" @default.
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