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- W2370596874 abstract "Six kinds of biguanidine-metal complexes were synthesized,and characterized by IR,1H NMR and 13C NMR spectra.The interaction of the six complexes with calf thymus DNA was studied by the UV-visible spectra.The spectra showed hypochromism as the increasing of the ct-DNA,which suggested that the combination of the metal complexes and ct-DNA was caused by the intercalation.The binding constants of the six complexes Kb were calculated,resulting as 1.10×104,1.34×104,1.05×104,1.23×104,1.33×104 and 1.42×104 for complexesⅠ-Ⅵ.The value indicated that the comp Ⅵ,having the proper structure,showed the stronger binding ability to DNA than the other five complexes.The Gel electrophoresis showed that as the increase of the complexes,the cleavage of pBR322 DNA was more obvious.The results also prompted that the more beneficial to interaction with DNA,the smaller space factor of the complexes structure for the same metal ions and the greater metal ion radius of the same ligand.These may be related to complexes regulation of the ability of the structure." @default.
- W2370596874 created "2016-06-24" @default.
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- W2370596874 date "2009-01-01" @default.
- W2370596874 modified "2023-09-22" @default.
- W2370596874 title "Synthesis and DNA-binding properties of biguanidine-metal complexes" @default.
- W2370596874 hasPublicationYear "2009" @default.
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