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- W2370642023 abstract "For the comprehensive utilization of CO in off-gas of yellow phosphorus,chromatography GC-14C and gas stimulation through steel-vase container were used to research adsorbing removal of H2S and PH3 by activated carbon(AC) modified through acid and alkali.The results showed that it was minus first order and 23.77 kJ/mol of average adsorbing activation energy for adsorbing reaction of H2S on alkali modified carbon,and minus second order and 61.3 kJ/mol of average adsorbing activation energy for adsorbing reaction of PH3 on acid modified carbon with the order of first physisorption and then chemisorption;TG/DTA and pore size distribution indicated that main adsorbates were sulfur and sulfur oxides or phosphorus and phosphorus oxides;micropore with radius 1.5 nm made primary contribution for adsorbing removal of H2S and PH3;and mass loss of adsorbates occurred mainly in the stage of 0-100℃.A well feasible math model was induced according to mechanism of adsorbing reaction to forecast breakthrough curve." @default.
- W2370642023 created "2016-06-24" @default.
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- W2370642023 date "2007-01-01" @default.
- W2370642023 modified "2023-09-24" @default.
- W2370642023 title "Adsorbing removal of H_2S and PH_3 in off-gas of yellow phosphorus by activated carbon modified through acid and alkali" @default.
- W2370642023 hasPublicationYear "2007" @default.
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