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- W2370943851 abstract "The determination of the intrinsic kinetics in biphasic recognition chiral extraction(BRCE) of phenylsuccinic acid(PSA) enantiomers was studied,taking the extracton separation of PSA enantiomers as a first order process.The BREC system was established by adding hydroxypropyl-β-cyclodextrin(HP-β-CD) in aqueous phase and L-isobutyl tartrate(L-IBTA) in organic phase as chiral selector.The different parameters affecting the extraction rate such as agitation speed,interfacial area,initial enantiomers concentration in aqueous phase,HP-β-CD and L-IBTA concentration as well as pH in aqueous phase were separately studied.It was found that the extraction rate constant in BRCE of R-PSA and S-PSA is 32.95×10?5 m6?mol?2?s?1 and 16.18×10?5 m6?mol?2?s?1 at 278 K,respecting.The kinetic model of this BRCE system in phenylsuccinic acid extractive separation was founded." @default.
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- W2370943851 date "2012-01-01" @default.
- W2370943851 modified "2023-09-23" @default.
- W2370943851 title "Kinetics of phenylsuccinic acid reactive extraction by a biphasic recognition chiral extraction system" @default.
- W2370943851 hasPublicationYear "2012" @default.
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