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- W2370948843 abstract "Solid electrolyte Ce0. 8Gd0. 2- xYxO2- δ( x = 0,0.05,0.10) were prepared by sol-gel method. Structural characteristics of the samples were investigated by means of X-ray diffraction( XRD) and Raman spectroscopy. The electrical properties of Ce0. 8Gd0. 2- xYxO2- δ( x = 0,0. 05,0. 10) were analyzed by AC impedance spectroscopy. The results showed that all samples calcined at 800 ℃ crystallized in single cubic fluorite structure with the oxygen vacancies. The lattice parameter was decreased with the increasing of Y doped. The sample of X = 0. 05 Y doped has the highest electrical conductivity and the lowest activity energy( σ700 ℃= 5. 58 × 10- 3S· cm- 1,Eα= 0. 92 eV),which is higher than the electrical conductivity of Ce0. 8Gd0. 2O2- δsample without doping of Y( σ700 ℃= 5. 38 × 10- 3S ·cm- 1Eα= 1. 09 eV). So appropriate amount of double doped can improve the electrical conductivity and reduce the activity energy of Ce0. 8Gd0. 2- xYxO2- δ." @default.
- W2370948843 created "2016-06-24" @default.
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- W2370948843 date "2014-01-01" @default.
- W2370948843 modified "2023-09-23" @default.
- W2370948843 title "Preparation and Properties of Solid Electrolyte Ce_(0. 8)Gd_(0. 2- x)Y_xO_(2- δ)( x = 0,0. 05,0. 10)" @default.
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