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- W2371072554 abstract "The electrochemical method for the determination of metal chelate stability constants by means of potentiometric measurement with a mercury electrode has been applied to EDTA complexes of divalent metals at 30.0±0.1°in the presence of potassium nitrate. The basic principle of this method is based upon the exchange equilibria of the type HgY~(2-)+Me~(2+)??MeY~(2-)+Hg~(2+) The log K values of Hg, Cu, Pb, Zn, Cd, Mn, Ca, Mg, Sr, and Ba-EDTA chelates are found to be 21.66, 18.82, 17.99, 16.55, 16.49, 13.92, 10.92, 9.06, 8.88 and 8.05 respectively, which are in good agreement with those obtained by Schwarzenbach and by Reilley and Schmid who all studied the EDTA chelates with the same electrode but with different experimental procedures. The addition of metallic mercury into the solutions to be studied prior to potentiometric measurement as suggested by Schwarzenbach has been tested and found to be unnecessary. The time for attaining equilibria is almost the same, no matter whether the metallic mercury has been added or not." @default.
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- W2371072554 date "1964-01-01" @default.
- W2371072554 modified "2023-09-25" @default.
- W2371072554 title "MERCURY ELECTRODE IN THE STUDY OF COMPLEXES I. STABILITY CONSTANTS OF EDTA CHELATES OF BIVALENT METALS" @default.
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