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- W2372050750 abstract "A thermoregulated phosphite ligand OPGPP was synthesized and characterized by FTIR and 1HNMR.The complex of OPGPP and palladium chloride was used as the catalyst in the hydrogenation of oleic acid methyl ester.The reaction time,reaction temperature,hydrogen pressure and the dosage of catalyst were investigated.The optimum reaction conditions for the hydrogenation of oleic acid methyl ester were obtained as follows:reaction temperature 200 ℃,hydrogen pressure 7 MPa,the dosage of palladium chloride amounts to 0.12% of oleic acid methyl ester,n(palladium chloride)∶n(OPGPP) 1∶10,reaction time 4 h.Under the above conditions,the OH·V of products was 114 and the I·V of products was 25.The cycle performance of catalyst was also investigated.When the composite catalytic system was repeatedly used for four times,the OH·V of products was 102 and the I·V of products was 27." @default.
- W2372050750 created "2016-06-24" @default.
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- W2372050750 date "2009-01-01" @default.
- W2372050750 modified "2023-09-26" @default.
- W2372050750 title "A Study on Hydrogenation of Oleic Acid Methyl Ester with Phosphine Palladium Complexes" @default.
- W2372050750 hasPublicationYear "2009" @default.
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