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- W2372209986 abstract "Cu/γ-Al_2O_3 and Cu-Ni/γ-Al_2O_3 catalyst were prepared via temperatureprogrammed reduction.With these two catalysts phenol can be synthesized by direct hydroxylation of benzene.Factors affecting this reaction such as reaction temperature and reaction solvent were studied.Effects of nickel on the structure and character of the catalysts were investigated by H_2-TPR,XRD and EDS.Results showed that the reduction temperature of the precursor increased,the grain size of copper active constituent decreased,and copper atom number on the surface of the catalyst increased after adding Ni.It was also found that the activity and selectivity of benzene hydroxylation reaction over the Cu-Ni/γ-Al_2O_3 catalyst were higher than over the Cu/γ-Al_2O_3 catalyst.Under the reaction temperature of 70 °C and in water solution,the conversion of benzene was 32.4%,the selectivity to phenol was 93.3% and the yield of phenol was(30.2%.)" @default.
- W2372209986 created "2016-06-24" @default.
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- W2372209986 date "2009-01-01" @default.
- W2372209986 modified "2023-09-26" @default.
- W2372209986 title "Effect of Nickel on Cu-Ni/γ-Al_2O_3 Catalyst Used in Benzene Hydroxylation Reaction" @default.
- W2372209986 hasPublicationYear "2009" @default.
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