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- W2372315511 abstract "The catalytic performance of several organotitanium compounds for transesterfication of dimethyl oxalate with phenol was investigated. The results showed that the catalytic activities and selectivities were in the order: Cp2 TiCl2 Ti( OPh)4 Ti( OBu)4 TiO( acac)2 Ti( OEt)4 Ti( OEt)4. This means that Cp2TiCl2was an efficient transesterfication catalyst compared to the others. Under the optimal conditions( n( Cp2TiCl2) = 0. 001 mol,n( DMO) =0. 3 mol,n( Phenol) = 0. 2 mol,T =180 ℃,t =2 h),the conversion of phenol reached 4 4. 0%, and the yield of MPO and DPO were 37. 8% and 6. 1%,respectively,while the total transesterfication selectivity was 99. 8%." @default.
- W2372315511 created "2016-06-24" @default.
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- W2372315511 date "2014-01-01" @default.
- W2372315511 modified "2023-09-27" @default.
- W2372315511 title "Organotitanium Compound Catalysts for Transesterification of Dimethyl Oxalate with Phenol" @default.
- W2372315511 hasPublicationYear "2014" @default.
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