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- W237261566 abstract "Abstract Diorganothallium transition metal complexes of the general formula R 2 Tl—ML n with ML n = M(CO) 2 LCp (M = Mo, W; L = CO, PPh 3 ) are obtained by protolytic reactions, redistribution reactions or by methatetic reactions, and are characterized spectroscopically and by chemical reactions. For ML n = Cr(CO) 3 Cp, Fe(CO) 2 Cp and Co(CO) 4 R 3 Tl and Tl(ML n ) 3 can always be isolated. In the case of Me 2 Tl—M(CO) 3 Cp (M = Mo, W) variable temperature NMR measurements gave evidence for a symmetrisation—redistribution equilibrium 3 R 2 Tl—ML n —ML n ⇌ R 3 Tl + Tl(ML n , which generally determines the stability of the diorganomthallium transition metal complexes." @default.
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- W237261566 date "1978-02-01" @default.
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- W237261566 title "Diorganothallium-übergangsmetall-komplexe, R2Tl—Mln" @default.
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- W237261566 doi "https://doi.org/10.1016/s0022-328x(00)81297-8" @default.
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