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- W2372653722 abstract "Poly(tert-butyl methacrylate)(PtBMA-Cl) and poly(tert-butyl methacrylate)-b-poly(N-isopro-pylacrylamide) (PtBMA-b-PNIPAM) are prepared by atom transfer radical polymerization using 1-chlorophenylethane (1-PECl) as initiator and CuCl/N,N,N',N,N-pentamethyldiethylenetriamine(PMDETA) as catalyst.The amphiphilic block copoiymer(PtBMA-b-PNIPAM) self-assembles into micelles in the selective solvent.The structure and composition of PtBMA-b-PNIPAM are characterized by IR spectroscopy and ~1HNMR,and the relative molecular weight of the block copolymers are determined by gel permeation chromatography(GPC).The morphologies and behavior of thermo-responsive block copolymers in solution are investgated by TEM and DLS." @default.
- W2372653722 created "2016-06-24" @default.
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- W2372653722 date "2010-01-01" @default.
- W2372653722 modified "2023-09-26" @default.
- W2372653722 title "Synthesis of Poly(tert-butyl(meth) acrylate) -b-Poly(N-isopropylacrylamide) by Atom Transfer Radical Polymerization and Their Self-assembly Behavior" @default.
- W2372653722 hasPublicationYear "2010" @default.
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