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- W2372809918 abstract "Polynitrogen anion N5-is an important intermediate in the synthesis of N5+N5-,an energetic material.The synthesis,reaction mechanism,characterization and stability of arylpentazoles were summarized,and the efforts to obtain N5-by dearylation of arylpentazoles were also discussed.It was found that arylpentazoles were synthesized successfully using arylamines as starting material and characterized by means of Raman spectroscopy,NMR and single crystal X-ray diffracion analysis at a low temperature.The effect of substituted groups and solvent on the stability of arylpentazoles were investigated,and the signal of N5-was detected by electrospray ionization mass spectrometry and laser desorption ionization mass spectrometry in negative-ion mode.However,it was concluded experimentally that it was difficult to obtain N5-by chemical methods because of the bad stability of arylpentazoles." @default.
- W2372809918 created "2016-06-24" @default.
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- W2372809918 date "2012-01-01" @default.
- W2372809918 modified "2023-09-23" @default.
- W2372809918 title "Research progress of polynitrogen anion N_5" @default.
- W2372809918 hasPublicationYear "2012" @default.
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