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- W2373149106 abstract "Mononitration of toluene with nitric acid in the presence of sodium bisulfate was studied. The results show that when the nitrated reaction temperature was controlled at 45 ℃, and the nitrated reaction time was 60 min, nitration of toluene with 95% nitric acid as nitrating reagent in the presence of acetic anhydride and 1.8 g sodium bisulfate catalyst exhibited a high regioselectivity, with ortho-para isomer ratio up to 1.09 in product distribution of toluene nitration, greatly below ortho-para isomer ratio of 1.67 in the product distribution of toluene nitration with sulfonitric acid as catalyst, and gave a yield of 99.9%. The catalyst could be reutilized up to five times with little decrease in activity. It is a kind of prowising nitrated reaction catalyst to replace sulfonitric acid, and has a vast value of industrialization exploitation." @default.
- W2373149106 created "2016-06-24" @default.
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- W2373149106 date "2008-01-01" @default.
- W2373149106 modified "2023-09-22" @default.
- W2373149106 title "Nitration of Toluene in the Presence of Sodium Bisulfate Catalyst" @default.
- W2373149106 hasPublicationYear "2008" @default.
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