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- W2373208532 abstract "Structural modifications in LiNiO2 induced by doping of Al, Co and Mn were investigated by XRD and EXAFS. Diffraction experiments show that doping does not modify the phase as LiNiO2, and all structures belong to the R3m group, however, doping of Al, Co and Mn, decreases the size of the unit cell, and limits the cation mixing in lithium layers. From EXAFS data fitting one may see that doping of Al, Co and Mn decreases the Debye-Waller factor of the first shell of Ni-O and weakens the John-Teller distortion of the Ni?髥O6 octahedron. Doping by Al and Co in LiNiO2 also decreases the Ni-O bond length while the effect on bond length is not obrious with Mn doping. All dopings decrease also the second shell Ni-Ni bond length. Moreover, doping of Co and Mn decreases the Debye-Waller factor of the second shell increasing the ordering of the Ni-Ni shell, while Al doping increases the Debye-Waller factor and slightly enhances the disorder degree of the Ni-Ni shell." @default.
- W2373208532 created "2016-06-24" @default.
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- W2373208532 date "2006-01-01" @default.
- W2373208532 modified "2023-09-25" @default.
- W2373208532 title "Structural Changes Induced by Doping in LiNiO_2" @default.
- W2373208532 hasPublicationYear "2006" @default.
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