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- W2373460988 abstract "As the polymeric liquids reported in our previous work[1], the product of square root of internal pressure l and molar volume Vm for the general small molecular liquids at 298.15K is also directly proportional to their van der Waals volume Vvdw, and both have same proportional coefficients. This indicates that the values of lVm for all kinds of liquids have same group additivity. Therefore, using their experimental values of internal pressure and molar volume, a group contribution method of lVm, which can be used to predict the internal pressure of various organic liquids contained polymeric liquids at 298.15K is established. This method is applicable not only to non-polar and slight polar liquids, but also to strong polar and associated liquids. The famous Smalls group contribution of solubility parameter is only a specific example of this work. The prediction results of l for 120 organic liquids and polymeric liquids show that the consistency with experimental values is satisfactory." @default.
- W2373460988 created "2016-06-24" @default.
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- W2373460988 date "2004-01-01" @default.
- W2373460988 modified "2023-09-26" @default.
- W2373460988 title "Prediction of Internal Pressure for Liquids and Polymers" @default.
- W2373460988 hasPublicationYear "2004" @default.
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