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- W2373702936 abstract "(R)-(E)-1-(2,4-Dichlorophenyl)-2-(1,2,4-triazol-1-yl)-4,4-dimethyl-1-penten-3-ol (II) was synthesizedby resolution of the diastereomer esters obtained from diniconazole (I) and (-)-menthoxyacetyl acid, then the bioactivemonomer, (R)-(E)-1-(2,4-dichlorophenyl)-2-(1,2,4-triazol-1-yl)-4,4-dimethyl-1-penten-3-ol-acrylate (III), was syn-thesized by reacting II with acryloyl chloride, and the fungicide-polymers (IV, V, VI) containing II were obtained bythe radical polymerization of III and copolymerization of III with acrylic acid or methyl methacrylate. The hydrolysisresults of the fungicide-polymers showed that the release rate of active ingredients in a basic medium is higher than ina neutral or acidic medium. It was also indicated that V was characterized by a rapid initial release in the first few daysfollowed by a more gradual rate lasting several weeks and was potentially useful for the development of the commercialCRFs of pesticides, while IV and VI had much lower release rates with little initial release." @default.
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- W2373702936 date "2007-01-01" @default.
- W2373702936 modified "2023-09-26" @default.
- W2373702936 title "Syntheses of Fungicide-polymers Containing Chiral Diniconazole" @default.
- W2373702936 hasPublicationYear "2007" @default.
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