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- W2374022060 abstract "Experiments were conducted to investigate the formation of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans(PCDDs/Fs) from polycyclic aromatic hydrocarbons(PAHs) catalyzed by model fly ash.The typical PAHs,fluorine was taken as reaction material based on its similar chemical structure with PCDDs/Fs,and quartz sand mechanically mixed with copper chloride as model fly ash(MFA).The effects of copper chloride,ferric chloride,copper oxide and chlorine on PCDDs/Fs formation were compared.Results indicated that reaction moved according to de novo synthesis mechanism with the increase of oxidation ability of MFA,while increasing chlorinating ability moved reaction towards precursor formation mechanism.Higher oxidation and chlorinating ability of MFA resulted in increasing toxicity equivalence quantity(TEQ) of PCDDs/Fs,and the effect of chlorinating ability was more evident.Formation of PCDDs/Fs from fluorine catalyzed by MFA was the combined results of de novo synthesis mechanism and precursor compounds mechanism." @default.
- W2374022060 created "2016-06-24" @default.
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- W2374022060 date "2007-01-01" @default.
- W2374022060 modified "2023-09-26" @default.
- W2374022060 title "Experimental study of PCDDs/Fs formation from fluorene catalyzed by model fly ash" @default.
- W2374022060 hasPublicationYear "2007" @default.
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