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- W2374098476 abstract "On the basis of phase transition theory,the characteristics of synthetic ZSM-5/mordenite(MOR) sieves solution,the growth progress of molecular sieves crystals were investigated by estimating solution surface energy,X-ray diffraction,scanning electron microscope and energy spectroscopy analyses.The results show that obvious solid phase transition exists between ZSM-5 and MOR molecular sieves,which are characterized by formation free energy,phase interface,phase relationship,habit plane and strain energy.Together with liquid-solid,solid-solid,and solid-liquid phase transition mechanism,the synthetic mechanism of ZSM-5/MOR can be explained as:the phase separation of solution appears on the first stage;as a result,the solution is separated into silicon-rich phase to produce ZSM-5 and aluminum-rich phase to produce MOR.However,the phases are metastable because the surface energy of ZSM-5 sieves is larger than that of MOR.Thus,on the late stage of nucleation,ZSM-5 sieves transit to MOR gradually until intergrowth phase balance reaches.The above-mentioned explanation is also further proved by our experiments." @default.
- W2374098476 created "2016-06-24" @default.
- W2374098476 creator A5077946944 @default.
- W2374098476 date "2010-01-01" @default.
- W2374098476 modified "2023-09-23" @default.
- W2374098476 title "SYNTHESIS MECHANISM OF ZSM-5/MORDENITE INTERGROWTH MOLECULAR SIEVES II——THE PHASE TRANSITION PROCESS" @default.
- W2374098476 hasPublicationYear "2010" @default.
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