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- W2374169974 abstract "Sulfoxides are converted to the corresponding sulfides in good yields by low valent tungsten agents derived from WCl_6-BuLi(1)and WCl_6-Zn (2).Pyridine-N-Oxides are also reduced easily with 1 to give the corresponding pyridines in almost quantitative yields. A yellow solid WCl_4 (THF)_n is isolated from the reaction of one mole of WCl_6 and two mole of n-BuLl in tetrahydrofuran (THF)at low temperature, and its composition is established by using ESCA. IR, ~1H and ~12C NMR. Reaction of WCl_4 (THF)n with excess of pyridine gives the known WCl_4(C_6H_5N)_2." @default.
- W2374169974 created "2016-06-24" @default.
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- W2374169974 date "1987-01-01" @default.
- W2374169974 modified "2023-09-24" @default.
- W2374169974 title "Low valent tungsten reaction——Composition studies and reactions with sulfoxides and pyridine-N-oxides" @default.
- W2374169974 hasPublicationYear "1987" @default.
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