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- W2374225948 abstract "Methods for predicting the thermodynamic properties of natural fluids over a large range of concentration, temperature and pressure are presented. With careful choice of phenomenology and parameterization, predictions can be made with accuracies similar to the experimental data. Results presented for the NaCl-CO_2-CH_4-H_2O system suggest that these modeling methods can be used to extrapolate experimental measurements to high pressure and temperature regions difficult to access by experimental methods. For species such as CH_4 and CO_2, which are nonpolar and weakly interacting, a corresponding states representation yields results that are highly accurate and depend on only two temperature and pressure independent parameters. Predictions with such models of fluid/fluid coexistence at high temperature and pressures are within experimental accuracy. The role of molecular dynamics and Monte Carlo simulations in developing thermodynamic representations of natural system are discussed. For closed shell and nonpolar systems, simulation results agree very well with experimental data. Polar systems (H_2O) at sufficiently high temperatures are also well described. On the other hand, the simulations for polar systems at low temperatures yield results only in qualitative agreement with data. Efforts to improve simulation methods for these systems are in progress." @default.
- W2374225948 created "2016-06-24" @default.
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- W2374225948 date "2004-01-01" @default.
- W2374225948 modified "2023-09-25" @default.
- W2374225948 title "Modeling Geological Fluids to High Temperatures and Pressures" @default.
- W2374225948 hasPublicationYear "2004" @default.
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