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- W2375123571 abstract "Two kinds of titania modified the inner surface of mesoporous slilcate MCM-41 (MCMTiO2 and MCM-Ti-TiO2) were synthesized by precursor tetrabutyltitanate and calcined MCM-41. The samples were characterized by XRD, FTIR, nitrogen adsorption/desorption at 77K and solid state diffuse reflectance UV-vis spectroscopy. XRD suggested that a long-range a long-range order kept in the hexagonal phase of titania modified MCM-41. Tetrabutyltitanate cocondensation with the pendant OH groups of MCM-41 via Si-O-Ti bonds and titania modified the inner walls of MCM-41. Titania on the inner walls of modified MCM-41 was estimated monolayer or two-layer according to the results of nitrogen adsorption/desorption isotherms. In UV-vis spectra, titania modified MCM-41 had significant blue shift compared to bulk TiO2 which is attributed to the well known quantum size effect for semiconductor as the particle size decreases." @default.
- W2375123571 created "2016-06-24" @default.
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- W2375123571 date "2001-01-01" @default.
- W2375123571 modified "2023-09-28" @default.
- W2375123571 title "Preperation and Characterization of Monolayered or Two-layered Titania Modified Mesoporous Molecular Sieves MCM-41" @default.
- W2375123571 hasPublicationYear "2001" @default.
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