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- W2375196825 abstract "The title complex [Co_2(bte)_3(NCS)_4(H_2O)_2]_n(bte=1,2-bis(triazol-1-yl)ethane)has been prepared and characterized.Single-crystal X-ray analysis reveals that the complex crystallizes in space group Pī with a=7.796 2(2),b=8.340 7(4),c=14.773 5(5),α=86.835(2),β=76.203 1(9),γ=80.583(3)°.The crystal consists of two discrete complexes,[Co(bte)2(NCS)2] and [Co(bte)(NCS)2(H2O)2].The structure of [Co(bte)2(NCS)2] demonstrates a one-dimensional neutral chain through bte-bridge,in which the Co(II)atom is in a distorted octahedral environment formed by four nitrogen atoms of the triazoles and two nitrogen atoms from two trans thiocyanato liagnds.The structure of [Co(bte)(NCS)2(H2O)2] consists of neutral chain containing Co(II)bridged by bte molecules.The six-co-ordination of Co2+ is achieved by means of two trans NCS-ions and water molecules.The IR spectra have also been investigated." @default.
- W2375196825 created "2016-06-24" @default.
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- W2375196825 date "2008-01-01" @default.
- W2375196825 modified "2023-09-24" @default.
- W2375196825 title "Synthesis and Crystal Structure of a Coordination Polymer [Co_2(bte)_3(NCS)_4(H_2O)_2]_n" @default.
- W2375196825 hasPublicationYear "2008" @default.
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