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- W2375304518 abstract "The needle-like nanohydroxyapatite crystals(HA) were surface-grafted with poly(e-caprolactone)(PCL) by ring-opening polymerization of e-caprolactones,and the effects of HA on the crystallization behavior of PCL were investigated by FTIR,XRD,DSC and PLM.The results show that HA promoted nucleation of PCL,but confined the degrees of PCL crystallinity,so the degrees of PCL crystallinity in the HA-PCL composite biomaterials were lower than the degree of pure PCL crystallinity.Moreover,the HA-PCL composite biomaterials could produce distinct ring-banded spherulites with the regular Maltese cross only when the HA mass fraction was 1% and the temperature was up to 45℃.In addition,increasing of the HA mass fraction had no influence on the degrees of PCL crystallinity and the crystalline structures." @default.
- W2375304518 created "2016-06-24" @default.
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- W2375304518 date "2007-01-01" @default.
- W2375304518 modified "2023-09-23" @default.
- W2375304518 title "Crystallization behavior of nanosized hydroxyapatite-poly(ε-caprolactone) composite biomaterials" @default.
- W2375304518 hasPublicationYear "2007" @default.
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