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- W2375563123 abstract "By means of SEM observation and complex AC impedance,the effects of the Pt/YSZ electrode sintering technics on its characteristics were studied.The investigation indicates that the resistance of the electrode increases and the response time of the oxygen sensor decreases as the sintering temperature is lowered,but the rate determining step(RDS) of the O2/O2-electrode reaction remains unchanged(above 600℃,the diffusion of adsorbed oxygen atoms on the Pt surface towards the YSZ;below 500℃,the dissociative adsorption of oxygen molecules on the Pt surface near the Pt/YSZ boundary);heating/cooling rate affects the interfacial resistance of the Pt/YSZ electrode and the response time of the oxygen sensor badly,the increase of cooling rate can even give a sudden change to the activation energy of the electrode reaction(above 600℃,the activation energy increases from 169kJ/mol to(217±4)kJ/mol suddenly);Pt/YSZ electrode has its best sintering technics when it operates below 500℃,the best sintering temperature and heating/cooling rate are 700℃ and 0.5-1℃/min respectively." @default.
- W2375563123 created "2016-06-24" @default.
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- W2375563123 date "2008-01-01" @default.
- W2375563123 modified "2023-09-23" @default.
- W2375563123 title "Study of the Pt/YSZ electrode sintering technics" @default.
- W2375563123 hasPublicationYear "2008" @default.
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