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- W2375829614 abstract "Two new complexes: [Cu(HCP)(TBZ)](NO3)2·(H2O)2 (1) and [Cu(HCP)(HPB)](NO3)2·(H2O)1.5 (2), where HCP=ciprofloxacin, TBZ=2-(4′-thiazolyl)benzimidazole, and HPB=2-(2-pyridyl) benzimidazole, were synthesized and characterized. Complex 1 crystallizes in the triclinic space group P1 in a unit cell of a=0.909 5(2) nm, b= 1.330 1(3) nm, c=1.355 2(3) nm, α=93.518(3)°, β=97.192(3)°, γ=106.361(3)°, V=1.552 6(6) nm3, Z=2, Dc=1.598 g·cm-3, μ=0.849 mm-1. The complexes were assayed against gram-positive and gram-negative bacteria by doubling dilutions method, and the interaction of the complexes to DNA was investigated by electronic absorption spectroscopy, fluorescence spectroscopy, viscosity measurement and agarose gel electrophoresis. The results show that the complexes have good antibacterial activities, could interact with DNA by an intercalative mode, and cleave pBR322DNA in the presence of vitamin C in the involvement of the hydroxyl radical in the cleavage process." @default.
- W2375829614 created "2016-06-24" @default.
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- W2375829614 date "2010-01-01" @default.
- W2375829614 modified "2023-09-25" @default.
- W2375829614 title "Synthesis, Antibacterial Activities of Copper(II) Complexes with Ciprofloxacin and TBZ or HPB and Their DNA Interactions" @default.
- W2375829614 hasPublicationYear "2010" @default.
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