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- W2376256960 abstract "Depolymerizing copper(I) phenylacetylide [Cu(C≡CPh)]n with cyclohexyl isocy- anide (CNCy) gave a tetranuclear copper(I) complex Cu4(CNCy)4(μ-η1-C≡CPh)2(μ3-η1,η1, η2-C≡ CPh)2. Crystal data: C30H32Cu2N2, Mr = 547.66, space group P1, a = 8.6448(1), b = 11.5772(2), c = 14.6666(4) ?, α = 88.387(2), β = 86.826(2), γ = 68.222(1)°, V = 1360.97(5) ?3, Z = 2, F(000) = 568, Dc = 1.336 g/cm3, μ = 1.582 mm-1, the final R = 0.0629 and wR = 0.1282 for 3257 observed reflections with I 2σ(I). The phenylacetylide adopts μ-η1 and μ3-η1,η1,η2 bonding modes. The compound shows intense luminescence in the solid state." @default.
- W2376256960 created "2016-06-24" @default.
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- W2376256960 date "2005-01-01" @default.
- W2376256960 modified "2023-09-27" @default.
- W2376256960 title "Luminescent Tetranuclear Copper(I) Phenylacetylide Complex with Cyclohexyl Isocyanide" @default.
- W2376256960 hasPublicationYear "2005" @default.
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