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- W2376417078 abstract "La0.68Gd0.2Mg0.12Ni3.3Co0.3Al0.1 hydrogen storage alloys were prepared by induction melting and then annealed at different temperature(1173-1273K) in the closed container for 16h.The effect of annealing temperature on the microstructure and electrochemical properties of La0.68Gd0.2Mg0.12Ni3.3Co0.3Al0.1 were investigated by means of inductively coupled plasma(ICP),X-ray diffraction(XRD),electron probe micro-analysis(EPMA) and electrochemical measurements.The results showed that the A5B19 alloys mainly consisted of Ce5Co19-type(Pr5Co19-type),PuNi3-type and CaCu5-type phase.Meanwhile,with increasing annealing temperature,Pr5Co19-type phase abundance in annealed alloys increased,and Ce5Co19-type phase abundance decreased.The Pr5Co19-type phase abundance was 87.75wt%,and Ce5Co19-type phase abundance was only 0.78wt% when annealing temperature was 1273K.The electrochemical measurements showed that these alloys had little effects on activation performance under different annealing temperature,but it was great impact on electrode capacity and cycle stability.The discharge capacity of the alloys reached 373.01mAh/g when annealing temperature was 1273K.After 100 charge-discharge cycles,the discharge capacity retention rate(S100)of the alloy electrode(T=1273K) reached 90.2%." @default.
- W2376417078 created "2016-06-24" @default.
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- W2376417078 date "2012-01-01" @default.
- W2376417078 modified "2023-09-27" @default.
- W2376417078 title "Effects of annealing treatment on microstructure and electrochemical properties of La_(0.68)Gd_(0.2)Mg_(0.12)Ni_(3.3)Co_(0.3)Al_(0.1) hydrogen storage alloys" @default.
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