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- W2376576688 abstract "The electrochemical behavior of p-phenylenediamine on platinum electrode was investigated by voltammeter.It was found that p-phenylendiamine exhibits a pair of nice reversible redox waves,the cathodic peak(II)at +0.19 V,the anodic peak(Ⅰ)at +0.25 V(vs.Ag/AgCl,saturation KCl)in 0.1 mol/L PBS.The electrochemical behavior of p-phenylendiamine in different support electrolytes,and different scanning rate was studied.The results showed that the electronic number and the proton number were the same involving in the oxidation of p-phenylendiamine.The electrode reaction of p-phenylendiamine was an adsoption-controlled process.The analyst time was short,easy and so on.The linear range for the determination of p-Phenylendiamine is 3.24 mg/L~108.14 mg/L,the regression equation was I=973.35C+81.318,and the regression coefficient was 0.9990.The detection limit was 1.1 mg/L.The electrichemical analysis method of p-phenylendiamine was set up and determined in hair dyes.The average rate of recovery(n =11) was 97%~ 107%,the relative standard deviation(n =11)was 1.57% for 43.2 mg/L p-phenylendiamine.The developed method has been applied for the determination of p-phenylendiamine in hair dyes with good result." @default.
- W2376576688 created "2016-06-24" @default.
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- W2376576688 date "2008-01-01" @default.
- W2376576688 modified "2023-09-23" @default.
- W2376576688 title "Determination of p-phenylenediamines in Hair Dyes by Square Wave Stripping Voltammeter" @default.
- W2376576688 hasPublicationYear "2008" @default.
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