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- W2376865147 abstract "Cationic polymerizations of 1,3 pentadiene(PD) by Me 3SiCl(TMSCl)/EtAlCl 2 initiating system were studied. By the introduction of TMSCl, the polymer yield prepared by EtAlCl 2 is greatly increased, and the polymerization rate of TMSCl/EtAlCl 2 system is 6 times higher than that of EtAlCl 2. The molecular weight of the polymer is also raised by adding TMSCl and shows a maximum in the range of [TMSCl]/[EtAlCl 2]=0~1. These observations indicate that TMSCl/EtAlCl 2 initiating system has an higher activity for cationic polymerization of PD than EtAlCl 2 alone. 1H NMR results show that the polymerization is indeed initiatied by EtAlCl 2 in combination with HCl resulting from hydrolysis of TMSCl by adventitious water." @default.
- W2376865147 created "2016-06-24" @default.
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- W2376865147 date "2000-01-01" @default.
- W2376865147 modified "2023-09-25" @default.
- W2376865147 title "Me_3SiCl/EtAlCl_2 INITIATING SYSTEM FOR CATIONIC POLYMERIZATION OF 1,3-PENTADIENE" @default.
- W2376865147 hasPublicationYear "2000" @default.
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