Matches in SemOpenAlex for { <https://semopenalex.org/work/W2377079119> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2377079119 abstract "A new terpyridine-functionalized dithioester was synthesized as a chain transfer agent in the reversible addition fragmentation chain transfer polymerization ( RAFT) of N-isopropylacyamide ( NIPAAm). The polymerization showed an first-order kinetics and the molecular weight increased linearly with conversion,indicating that the terpyridine-functionalized dithioester is an efficient chain transfer agent for the RAFT polymerization of NIPAAm. The terpyridine-functionalized poly ( N-isopropylacyamide) ( tpy-PNIPAAm) not only displays similar phase transition as PNIPAAm,but also have the coordination ability via terpyridine,which were further used to construct macromolecular-metal complex with ferrous ions as model metal ions. The appearance of a strong absorption at 555 nm in UV-Vis spectrum revealed the formation of macromolecular-metal complex,indicating the strong coordination ability of tpy-PNIPAAm to metal. Cloud point method and dynamic light scattering ( DLS ) were used to characterize the thermosensitivity of tpy-PNIPAAm and macromolecular-metal complex. The results showed that the macromolecular-metal complex could self-assemble into nanoparticles in aqueous solution due to the amphiphilic property The macromolecular-metal complex solution showed a similar phase transition as PNIPAAm. In addition,the nanoparticles of the macromolecular-metal complex in aqueous solution were stable even at temperature above the lower critical solution temperature (LCST) due to electrostatic repulsion. This work indicated the great potentials of tpy-PNIPAAm as carriers for the delivery of therapeutic radioisotopes." @default.
- W2377079119 created "2016-06-24" @default.
- W2377079119 creator A5009901155 @default.
- W2377079119 date "2010-01-01" @default.
- W2377079119 modified "2023-09-23" @default.
- W2377079119 title "SYNTHESIS OF TERPYRIDINE-FUNCTIONALIZED POLY(N-ISOPROPYLACYLAMIDE)S AND THEIR METAL COMPLEXES" @default.
- W2377079119 hasPublicationYear "2010" @default.
- W2377079119 type Work @default.
- W2377079119 sameAs 2377079119 @default.
- W2377079119 citedByCount "0" @default.
- W2377079119 crossrefType "journal-article" @default.
- W2377079119 hasAuthorship W2377079119A5009901155 @default.
- W2377079119 hasConcept C111998727 @default.
- W2377079119 hasConcept C121120078 @default.
- W2377079119 hasConcept C14631669 @default.
- W2377079119 hasConcept C155672457 @default.
- W2377079119 hasConcept C15920480 @default.
- W2377079119 hasConcept C159985019 @default.
- W2377079119 hasConcept C171250308 @default.
- W2377079119 hasConcept C178790620 @default.
- W2377079119 hasConcept C184651966 @default.
- W2377079119 hasConcept C185592680 @default.
- W2377079119 hasConcept C188027245 @default.
- W2377079119 hasConcept C188109995 @default.
- W2377079119 hasConcept C191897082 @default.
- W2377079119 hasConcept C192562407 @default.
- W2377079119 hasConcept C199164860 @default.
- W2377079119 hasConcept C204389451 @default.
- W2377079119 hasConcept C2781350956 @default.
- W2377079119 hasConcept C34594497 @default.
- W2377079119 hasConcept C44228677 @default.
- W2377079119 hasConcept C521977710 @default.
- W2377079119 hasConcept C544153396 @default.
- W2377079119 hasConcept C55493867 @default.
- W2377079119 hasConcept C75473681 @default.
- W2377079119 hasConcept C9132879 @default.
- W2377079119 hasConceptScore W2377079119C111998727 @default.
- W2377079119 hasConceptScore W2377079119C121120078 @default.
- W2377079119 hasConceptScore W2377079119C14631669 @default.
- W2377079119 hasConceptScore W2377079119C155672457 @default.
- W2377079119 hasConceptScore W2377079119C15920480 @default.
- W2377079119 hasConceptScore W2377079119C159985019 @default.
- W2377079119 hasConceptScore W2377079119C171250308 @default.
- W2377079119 hasConceptScore W2377079119C178790620 @default.
- W2377079119 hasConceptScore W2377079119C184651966 @default.
- W2377079119 hasConceptScore W2377079119C185592680 @default.
- W2377079119 hasConceptScore W2377079119C188027245 @default.
- W2377079119 hasConceptScore W2377079119C188109995 @default.
- W2377079119 hasConceptScore W2377079119C191897082 @default.
- W2377079119 hasConceptScore W2377079119C192562407 @default.
- W2377079119 hasConceptScore W2377079119C199164860 @default.
- W2377079119 hasConceptScore W2377079119C204389451 @default.
- W2377079119 hasConceptScore W2377079119C2781350956 @default.
- W2377079119 hasConceptScore W2377079119C34594497 @default.
- W2377079119 hasConceptScore W2377079119C44228677 @default.
- W2377079119 hasConceptScore W2377079119C521977710 @default.
- W2377079119 hasConceptScore W2377079119C544153396 @default.
- W2377079119 hasConceptScore W2377079119C55493867 @default.
- W2377079119 hasConceptScore W2377079119C75473681 @default.
- W2377079119 hasConceptScore W2377079119C9132879 @default.
- W2377079119 hasLocation W23770791191 @default.
- W2377079119 hasOpenAccess W2377079119 @default.
- W2377079119 hasPrimaryLocation W23770791191 @default.
- W2377079119 hasRelatedWork W1951995397 @default.
- W2377079119 hasRelatedWork W1971799132 @default.
- W2377079119 hasRelatedWork W1979677485 @default.
- W2377079119 hasRelatedWork W1995891189 @default.
- W2377079119 hasRelatedWork W2004806731 @default.
- W2377079119 hasRelatedWork W2004861457 @default.
- W2377079119 hasRelatedWork W2016602688 @default.
- W2377079119 hasRelatedWork W2022558779 @default.
- W2377079119 hasRelatedWork W2030835540 @default.
- W2377079119 hasRelatedWork W2069253900 @default.
- W2377079119 hasRelatedWork W2105674927 @default.
- W2377079119 hasRelatedWork W2115331600 @default.
- W2377079119 hasRelatedWork W2134273401 @default.
- W2377079119 hasRelatedWork W2154001618 @default.
- W2377079119 hasRelatedWork W2165697021 @default.
- W2377079119 hasRelatedWork W2167875344 @default.
- W2377079119 hasRelatedWork W2372393016 @default.
- W2377079119 hasRelatedWork W2524516557 @default.
- W2377079119 hasRelatedWork W2601556055 @default.
- W2377079119 hasRelatedWork W3182669730 @default.
- W2377079119 isParatext "false" @default.
- W2377079119 isRetracted "false" @default.
- W2377079119 magId "2377079119" @default.
- W2377079119 workType "article" @default.