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- W2377079283 abstract "Supported aqueous phase catalysts were prepared by means of immobilized sulfonated triphenyl phosphine rhodium complexes on a high sulface area supporter of SiO 2 Hydroformylation of propylene was catalyzed under the reaction conditions∶ T =100￣110 ℃, CO∶H 2=1∶1, p =20 MPa, =7 5×10 -5 , P/Rh=25 It is found that the TON is in the range of 194￣223 g butylaldehyde/(g Rh·h) and n/i ratio over 14 2, the lose of Rh was controlled in the range of 1×10 -9 ～4×10 -9 , the recycle problem of the Rh catalyst has been solved it shows that the SAP catalyst demostrates high activity, selectivity, and excellent stability The function of the catalyst related with its preparation method and reaction conditions were also discussed It proves that the SAP catalyst method is one of the best methods to realise heterogenization of homogenous reaction." @default.
- W2377079283 created "2016-06-24" @default.
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- W2377079283 date "1999-01-01" @default.
- W2377079283 modified "2023-09-23" @default.
- W2377079283 title "Preparation of Supported Aqueous Phase Catalysts and its Application for Hydroformylation of Propylene" @default.
- W2377079283 hasPublicationYear "1999" @default.
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