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- W2377181182 abstract "The conversion/space-velocity curves of oxychlorination catalysts are dependent on the routes of measurement. The curve obtained by measurement from high to low space is quite different from that obtained from low to high space velocity. The activity of the catalyst at high space velocities declines much faster than at low space velocities. The cause of this phenomenon is that the composition, structure and activity of the catalyst vary with the composition of the reactant. A coordination-reduction-oxidation catalytic mechanism is proposed to explain all the facts concerned. For an oxychlorination catalyst at a given temperature and feed composition, there is an space velocity at which a maximum conversion of HC1 is attained. In case the space is lower than this optimum one, the conversion of HC1 does not increase but decreases instead, because the 1. 2 dichloroethane which has been formed will be cracked to form HC1. The side reaction, oxidation of ethylene, is a parallel reaction catalyzed by CuCl_2." @default.
- W2377181182 created "2016-06-24" @default.
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- W2377181182 date "1980-01-01" @default.
- W2377181182 modified "2023-09-25" @default.
- W2377181182 title "KINETIC BEHAVIOUR AND MECHANISM OF OXYCHLORINATION CATALYST" @default.
- W2377181182 hasPublicationYear "1980" @default.
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