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- W2377306585 abstract "The thermal behavior of cation waterborne polyurethane(CWPU) was investigated by non-isothermal method and thermogravimetry(TG) technique in N2 atmosphere.The iterative iso-conversional methods were applied to calculate the activation energy Ea of dehydration and decomposition,and the most probable mechanism function G(α) was determined by means of the master plots method.The weightlessness of CWPU proceeds to completion by two distinct reactions.These two reactions overlap in the transition process(55%α60%).Kinetic parameters of the first reaction of weightlessness were:Ea =83.46kJ·mol-1,lnA/s-1 =19.78,and the mechanism function wasG(α)=[1-(1-α)1/2]2.And in the second reaction Ea = 95.61 kJ·mol-1,lnA/s-1=16.94,G(α)= α+(1-α)ln(1-α)." @default.
- W2377306585 created "2016-06-24" @default.
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- W2377306585 date "2012-01-01" @default.
- W2377306585 modified "2023-09-23" @default.
- W2377306585 title "Study on Thermal Behavior of Cation Waterborne Polyurethane by TGA Technology" @default.
- W2377306585 hasPublicationYear "2012" @default.
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