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- W2377694872 abstract "Uranium is the most extensively studied element in actinide chemistry.In the past few years,many uranyl coordination compounds had been synthesized,whereas the report on the U(Ⅳ) cooridination compounds is much less.Here we reported the synthesis,crystal structure and magnetic property of a novel U(Ⅳ) coordination compound UNa_2(pdc)_356H_2O(H_2pdc=pyridine-2,6-dicarboxylic acid).The title compound crystallized in the monoclinic space group P2_1/n,with unit cell parameters a=1.020 5(2) nm,b=2.222 1(4) nm,c=1.253 7(3) nm,β=94.98(3)°,V=2.832 3(10) nm~3,Z=4.The centered uranium atom is bonded to three pdc ligands via three nitrogen atoms and six oxygen atoms in a tricapped trigonal prismatic coordination.The temperature dependence of magnetic susceptibility reciprocal curve shows that the title compound has a paramagnetic behavior which obey to Curie-Weiss equation above 50 K(C=1.01 cm~35K5mol~-1, θ=-63.21 K)." @default.
- W2377694872 created "2016-06-24" @default.
- W2377694872 creator A5003232376 @default.
- W2377694872 date "2006-01-01" @default.
- W2377694872 modified "2023-09-25" @default.
- W2377694872 title "Synthesis,Structure and Magnetic Property of a Novel U(IV) Coordination Compound:UNa_2(pdc)_3·6H_2O" @default.
- W2377694872 hasPublicationYear "2006" @default.
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