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- W2378082215 abstract "The intramolecular aromatic-ring stacking interaction of mixed- ligand complex Pd(A)(UTP)~(2-)in the system pd~(2+)-A-UTP~(4-)has been determined by ~1HNMR,where A=1,10-phenanthroline(phen),2,2'-bipyridyl(bpy)and DL- tryptophan(trp~-);UTP~(4-)=uridine 5-triphosphate.The result indicates that it is the partial stacking between the uracil ring of UTP~(4-)and the heterocyclic ring of A that makes H(5),H(6)and H(1')in the UTP~(4-)shift upfield signifi- cantly.Accordingly,the order of aromatic-ring interaction in the mixed- ligand complex has been obtained as follows:Pd(phen)(UTP)~(2-)(?)Pd(bpy)(UTP)~(2-) Pd(trp)(UTP)~(3-)." @default.
- W2378082215 created "2016-06-24" @default.
- W2378082215 creator A5005902513 @default.
- W2378082215 date "1991-01-01" @default.
- W2378082215 modified "2023-09-25" @default.
- W2378082215 title "THE INTRAMOLECULAR AROMATIC-RING STACKING INTERACTION OF MIXED LIGAND PALLADIUM(II)COMPLEXES III.STUDIES ON THE Pd~(2+)-A-UTP~(4-)SYSTEMS BY HNMR" @default.
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