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- W2378097997 abstract "In this paper,electrochemical behaviour of Pb – 0. 3% Ag – 0. 06% Ca rolled alloy anode during the360 hours( 15 days) galvanostatic electrolysis in acid zinc sulphate electrolyte solution is investigated with Cyclic Voltammetry( CV) techniques. The phase composition of the anodic oxide layers during the electrolysis is observed using X-Ray Diffraction( XRD). The results reveal that the electrochemical oxidation processes and phase formation vary obviously during the electrolysis for it is a process indicating the formation and stabilization of anodic oxide layer. With the increasing electrolysis time,the anodic peak( Pb→PbSO4) mainly presents a rise trend in the first two days electrolysis. It keeps thereafter almost a constant value( 0. 25 mA / cm2). The anodic peak( Pb→PbSO4) gradually moves in the positive direction while the anodic peak( PbSO4→β- PbO2,PbO→α- PbO2) strongly moves in the negative direction. The cathodic peak( β- PbO2and α- PbO2→PbSO4) and( PbO and PbSO4→Pb) mainly present a rise trend and gradually move in the negative direction. Besides,the corrosion phase of the anodic oxide layers mainly consists of PbSO4,α- PbO2,β- PbO2,PbS2O3and Pb. With the increase of electrolysis time,the content of PbSO4presents a declining trend while the content of α- PbO2a rising trend. The preferred growth orientation of PbSO4and α- PbO2is( 021),( 121),( 212) and( 111)planes respectively." @default.
- W2378097997 created "2016-06-24" @default.
- W2378097997 creator A5075564691 @default.
- W2378097997 date "2013-01-01" @default.
- W2378097997 modified "2023-09-25" @default.
- W2378097997 title "Electrochemical Behaviors of Pb-0.3%Ag-0.06%Ca Rolled Alloy Anode During and After Zinc Electrowinning—— CV Investigations" @default.
- W2378097997 hasPublicationYear "2013" @default.
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