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- W2378098548 abstract "The [RhCl3(N–N)(DMSO)] complexes, the N–N being 2,2′-bipyridine (1), 1,10-phenanthroline (2), 4,7-diphenyl-1,10-phenanthroline (3), 4,4′-dimethyl-2,2′-bipyridine (4) and 1,10-phenanthroline-5,6-dione (5), have been synthesized and characterized with spectroscopic methods. The compounds 2–5 adopt mer- and complex 1 fac-structure. The molecular and electronic structure studies of mer- and fac-complexes with bpy and phen ligands at the DFT B3LYP level with 3-21G∗∗ basis set showed that mer-isomers are more stable. The cytostatic activity of the [RhCl3(N–N)(DMSO)] complexes against Caco-2 and A549 tumor cells have been studied. Their antibacterial activity have also been investigated. It has been found that the very promising biological activity show complexes 2, 3 and 4." @default.
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- W2378098548 date "2008-10-01" @default.
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- W2378098548 title "Synthesis, structure and antitumor activity of [RhCl3(N–N)(DMSO)] polypyridyl complexes" @default.
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- W2378098548 doi "https://doi.org/10.1016/j.jinorgbio.2008.07.004" @default.
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