Matches in SemOpenAlex for { <https://semopenalex.org/work/W2378312587> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W2378312587 abstract "Non-homogenous condensation of alkylferrocenes with acetone has been carried out in the presence of methyl alcohol and concentrated sulfurric acid. Two series of compounds, 2,2-bis(monoalkylferrocenyl)propanes and 2,2-bis(dialkylferrocenyl)propanes were isolated by column chromatography. It was found the (optimal) conditions were n(alkylferrocene)∶n(acetone)∶n(concentrated sulfuric acid)∶n(methyl (alcohol)=)1∶0.55∶2∶6.7, reaction time 4～6 h, and reaction temperature 80～90 ℃. The structures of these compounds were characterized by elemental analysis, IR, and ~(1)H NMR. The electrochemical properties of these compounds were investigated by cyclic voltammetry. The results indicated that the burning-rate catalytic (efficiency) of the title compounds showed a slow decrease with the increase of the alkyl chain length, and for the alkyl group with same carbon number, the more alkyl groups the stronger the electron repulsion and reducibility, and hense the higher the burning-rate catalytic activity. The effect of the structures, electrochemical properties, and catalytic activity on the burning-rate were also discussed." @default.
- W2378312587 created "2016-06-24" @default.
- W2378312587 creator A5061857428 @default.
- W2378312587 date "2004-01-01" @default.
- W2378312587 modified "2023-09-25" @default.
- W2378312587 title "Synthesis and Buring-rate Catalytic Property of 2,2-Bis(alkylferrocenyl)propane" @default.
- W2378312587 hasPublicationYear "2004" @default.
- W2378312587 type Work @default.
- W2378312587 sameAs 2378312587 @default.
- W2378312587 citedByCount "0" @default.
- W2378312587 crossrefType "journal-article" @default.
- W2378312587 hasAuthorship W2378312587A5061857428 @default.
- W2378312587 hasConcept C147789679 @default.
- W2378312587 hasConcept C155647269 @default.
- W2378312587 hasConcept C161790260 @default.
- W2378312587 hasConcept C17525397 @default.
- W2378312587 hasConcept C178790620 @default.
- W2378312587 hasConcept C185592680 @default.
- W2378312587 hasConcept C2776345496 @default.
- W2378312587 hasConcept C2777869211 @default.
- W2378312587 hasConcept C2778199549 @default.
- W2378312587 hasConcept C2780263894 @default.
- W2378312587 hasConcept C2781066024 @default.
- W2378312587 hasConcept C2781213060 @default.
- W2378312587 hasConcept C51724486 @default.
- W2378312587 hasConcept C52859227 @default.
- W2378312587 hasConceptScore W2378312587C147789679 @default.
- W2378312587 hasConceptScore W2378312587C155647269 @default.
- W2378312587 hasConceptScore W2378312587C161790260 @default.
- W2378312587 hasConceptScore W2378312587C17525397 @default.
- W2378312587 hasConceptScore W2378312587C178790620 @default.
- W2378312587 hasConceptScore W2378312587C185592680 @default.
- W2378312587 hasConceptScore W2378312587C2776345496 @default.
- W2378312587 hasConceptScore W2378312587C2777869211 @default.
- W2378312587 hasConceptScore W2378312587C2778199549 @default.
- W2378312587 hasConceptScore W2378312587C2780263894 @default.
- W2378312587 hasConceptScore W2378312587C2781066024 @default.
- W2378312587 hasConceptScore W2378312587C2781213060 @default.
- W2378312587 hasConceptScore W2378312587C51724486 @default.
- W2378312587 hasConceptScore W2378312587C52859227 @default.
- W2378312587 hasLocation W23783125871 @default.
- W2378312587 hasOpenAccess W2378312587 @default.
- W2378312587 hasPrimaryLocation W23783125871 @default.
- W2378312587 hasRelatedWork W1968925915 @default.
- W2378312587 hasRelatedWork W1969155714 @default.
- W2378312587 hasRelatedWork W1979436862 @default.
- W2378312587 hasRelatedWork W1995991837 @default.
- W2378312587 hasRelatedWork W2061784679 @default.
- W2378312587 hasRelatedWork W2078315441 @default.
- W2378312587 hasRelatedWork W2314302027 @default.
- W2378312587 hasRelatedWork W2350953585 @default.
- W2378312587 hasRelatedWork W2353158141 @default.
- W2378312587 hasRelatedWork W2353572347 @default.
- W2378312587 hasRelatedWork W2361658871 @default.
- W2378312587 hasRelatedWork W2370610168 @default.
- W2378312587 hasRelatedWork W2383636961 @default.
- W2378312587 hasRelatedWork W2384480776 @default.
- W2378312587 hasRelatedWork W2390963573 @default.
- W2378312587 hasRelatedWork W2399908931 @default.
- W2378312587 hasRelatedWork W3017166389 @default.
- W2378312587 hasRelatedWork W3044431038 @default.
- W2378312587 hasRelatedWork W76701373 @default.
- W2378312587 hasRelatedWork W2333481937 @default.
- W2378312587 isParatext "false" @default.
- W2378312587 isRetracted "false" @default.
- W2378312587 magId "2378312587" @default.
- W2378312587 workType "article" @default.