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- W2378537277 abstract "Two composites(denoted as 1-GO1and 1-GO2)were prepared from graphene oxide and the organic-inorganic complex{H6 [(H2 O) 1.5(H2 biim) 2(CH3 OH)] 2 [(H2 biim)(CH3 OH) 2 ][PW12 O40 ] 2 ·2CH3 CN} n(1)based-on 2,2′-biimidazole(denoted as H2 biim)molecules and phosphotungstic acid.The structure of as-synthesized composites was confirmed by infrared spectrometry and X-ray diffraction.Moreover,the proton conductivity of the two as-synthesized composites was measured by electrochemical impedance spectroscopy in a temperature range of 25-100 ℃ and a relative humidity range of 35%-98%.Results indicate that the structure characteristics of complex 1 are retained in two as-synthesized composites.Besides, 1-GO1and 1-GO2exhibit good proton conductivities of 1.26×10-3-2.2×10-3 S·cm-1 in the temperature range of 25-100℃ under a relative humidity of 98%;and they exhibit good proton conductivity of 0.64×10-3-2.2×10-3 S·cm-1 at 100℃in the relative humidity range of 35%-98%.Moreover,1-GO1and 1-GO2show better proton conductivities than complex1 at the same conditions." @default.
- W2378537277 created "2016-06-24" @default.
- W2378537277 creator A5047068303 @default.
- W2378537277 date "2014-01-01" @default.
- W2378537277 modified "2023-09-23" @default.
- W2378537277 title "Preparation and proton conductivity of composites of graphene oxide and 2,2′-biimidazole phosphotungstate" @default.
- W2378537277 hasPublicationYear "2014" @default.
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