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- W2378670518 abstract "Titanium-containing mesoporous molecular sieves Ti-HMS were synthesized through a neutral templating route based on hydrogen-bond interactions and self-assembly between neutral surfactant micelles(S~0) and neutral inorganic precursors(I~0)(namely S~0 I~0 templating route) by using the long-chain primary amine surfactants as templates. Influences of molar ratio of Si to Ti (v_(Si )/v_(Ti)) in reactants, Si sources, chain length in template molecule, Ti sources and the molar ratio of template to Si source (v_(HAD)/v_(TEOS)) on structure of Ti-HMS were investigated respectively. The catalytic oxidation performance of the synthesized Ti-HMS for styrene oxidation reaction was valued as well. The experimental results showed that Ti-HMS with high BET surface area and high ordered structure could be obtained when v_(Si)/v_(Ti)30. The pore volume and the pore size increase with the increase of the chain length in template molecule. The biggest BET surface area of Ti-HMS could be obtained when v_(HAD)/v_(TEOS) was (0.3). The influences of carbon chain length of organic titanium sources(such as TEOT、TPOT、TBOT) on structure and catalytic performance of Ti-HMS were not remarkable." @default.
- W2378670518 created "2016-06-24" @default.
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- W2378670518 date "2005-01-01" @default.
- W2378670518 modified "2023-09-25" @default.
- W2378670518 title "SYNTHESIS AND CATALYTIC OXIDATION PERFORMANCE OF Ti-HMS" @default.
- W2378670518 hasPublicationYear "2005" @default.
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