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- W2378977608 abstract "Hydrogen transfer reduction of acetophenone with isopropanol catalyzed by the complex of 2,6-bis(1-phenylimino)ethyl pyridine and dichloreis(triphenylphosphine) ruthenium was investigated.When the original molar ratio of acetophenone,ruthenium complex and KOH was 250∶1∶12,the hydrogen transfer hydrogenation of acetophenone gave 1-phenylethanol with a yield of 98.3% after 2 h of reaction at the temperature of 82 ℃.The effects of the reaction temperature,the substrate concentration,and the base etc.on the catalytic activity were investigated.The 2,6-pyridyl-diimine ruthenium complex exhibited good catalytic properties in the hydrogen transfer hydrogenation of ketones." @default.
- W2378977608 created "2016-06-24" @default.
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- W2378977608 date "2007-01-01" @default.
- W2378977608 modified "2023-09-24" @default.
- W2378977608 title "Hydrogen transfer hydrogenation of ketones with a 2,6-pyridyl-diimine Ruthenium complex" @default.
- W2378977608 hasPublicationYear "2007" @default.
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