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- W2379167902 abstract "A novel organic-inorganic hybrid nanocapsule was synt he sized by mini-emulsion copolymerization of styrene and 3-trimethoxysilyl propy l methacrylate (MPS) on the well dispersed octane droplet templates.The morpholo gy was characterized by transmission electron microscopy(TEM) and atom force mic roscopy(AFM).The microstructure parameters were characterized by gas adsorption instrument.The wall of the capsules was found to have microporous structures.Acc ording to these characteristics, a penetration model was established by using th e percolation theory.The penetration diffusion coefficient was dependent on poro sity and tortuosity.The kinetics of the penetration process was studied with ult raviolet-spectrophotometer and diffusion coefficient and tortuosity were calcul ated.Diffusion velocity increased with the increase of MPS content in capsules d ue to larger porosity;tortuosity was less in the cresol red-methanol system tha n in the anthracene-tetrahydrofuran system; and tortuosity nearly did not chang e with the MPS content in capsules. All these results were consistent with the p ercolation theory. The loading of the anthracene was also proved by infrared spe ctrometry, and the release diffusion coefficient was much smaller than that of l oading, but did not change with the MPS content in capsules." @default.
- W2379167902 created "2016-06-24" @default.
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- W2379167902 date "2005-01-01" @default.
- W2379167902 modified "2023-09-26" @default.
- W2379167902 title "Penetrating properties of novel organic-inorganic hybrid nanocapsules" @default.
- W2379167902 hasPublicationYear "2005" @default.
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