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- W2379511034 abstract "A series of fluorinated acrylate copolymers were synthesized by using monomers of perfluoroalkylethyl methylacrylate and acrylate with various length of side chain(n=4,8,12,16 and 18,respectively) as raw materials.The chemical structure and surface chemical composition of the prepared copolymer coatings were characterized by infrared spectroscopy(FT-IR) and X-ray photoelectron spectroscopy(XPS).Combining with the contact angle test,the corresponding contact angles of the coatings were measured,and their surface energy were analyzed.The crystallization of fluorinated acrylate copolymers were studied by differential scanning calorimetry(DSC),X-ray diffractometer(XRD) and polarizing microscopy(POM) for further analyzing the influence of different lengths of side chains on the water-and oil-repellent surface.The results show that the copolymers remain isotropic and have no crystallizability under room temperature when the acrylate's side chain length n=4,8 and 12;whereas when n=16 and 18,the crystallization can occur and the schlieren texture of layered smectic A phase can be obtained.Especially,when n=16,the alkyl side chains are more closely arranged and have a better synergy effect on the crystallization of fluorine-containing polymers,which indicates that the copolymer has excellent crystalline regularity and low surface energy,thus improving the stability of its water-and oil-repellence." @default.
- W2379511034 created "2016-06-24" @default.
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- W2379511034 date "2012-01-01" @default.
- W2379511034 modified "2023-09-26" @default.
- W2379511034 title "Study on Crystallization and Surface Properties of Fluorinated Acrylate Copolymers" @default.
- W2379511034 hasPublicationYear "2012" @default.
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