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- W2379527978 abstract "Coordination properties of a new tailed porphyrin iron complex, meso-mono [0-(4-dietheylamino) butylamidophenyl]triphenyloporphyrin iron(Ⅲ) chloride, PFe(Ⅲ)Cl, with bases are studied and the equilibrium constants for addition of these bases to PFe (Ⅲ)Cl in chloroform have been measured by spectral technique. Experimental results demonstrate that imidazole reacts with PFe (Ⅲ)Cl to form 2: 1 adduct in a single step, pyridine form 1:1 and 2:1 adduces in two steps and aliphatic amines form 1: 1 adducts only. There is a nearly linear relationship between the basieities of aliphatic amines and their equilibrium constants, log K=6.45pK_(?)-66.87." @default.
- W2379527978 created "2016-06-24" @default.
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- W2379527978 date "1985-01-01" @default.
- W2379527978 modified "2023-09-25" @default.
- W2379527978 title "REACTIONS AND EQUILIBRIUM CONSTANTS OF A TAILED PORPHYRIN IRON COMPLEX WITH A SERIES OF BASES" @default.
- W2379527978 hasPublicationYear "1985" @default.
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