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- W2379830930 abstract "Solid state reaction process and resulting products of Fe and hexagonal boron nitride (h-BN) were studied by ball milling the mixture of Fe and h-BN with Fe to h-BN volume ratio of 1∶12.5 and/or heat treating it under normal or high pressure. The 30h-milled Fe/BN mixture was annealed for 1h under an atmospheric pressure at 770 and 1170K, respectively. It was found that a small amount of γ′-Fe_4N was observed in the mixture annealed at 770K and a few γ′-Fe_4N was obtained at 1170K. All Fe atoms reacted with N atoms in the BN to form a single phase of e-Fe_xN when the mixture was milled for 60h or annealed for 1h under 4GPa at temperatures of 690-800K.However, no Fe-B phase was observed in the present experiment. Formation and phase transition of Fe-N alloy in the solid state reaction process as well as effect of pressure on the reaction and resulting products are discussed in the present paper. The mechanism of formation of Fe-N and Fe-B in the reaction process between Fe and BN are also investigated on use of Miedema model and thermodynamics and kinetics." @default.
- W2379830930 created "2016-06-24" @default.
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- W2379830930 date "2004-01-01" @default.
- W2379830930 modified "2023-09-27" @default.
- W2379830930 title "Thermodynamic and Kinetic Mechanism of Formation of Fe-N and Fe-B Alloy in the Solid-state Reaction Process between Iron and Boron Nitride" @default.
- W2379830930 hasPublicationYear "2004" @default.
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